Applied Chemical Engineering Thermodynamics

A Glimpse at Thermodynamics

The Zeroth and First Laws of Thermodynamics

  • Introduction
  • Objective and Approach
  • The Zeroth Law and the Ideal Gas Temperature
    • The Statement
    • Is it Really a Law?
    • Temperature: the Common Property of Systems in Thermal Equilibrium
    • The Ideal Gas Temperature Scale
  • The First Law
    • Background and Statement
    • The Analytical Expression
    • Comments

The Second Law of Thermodynamics

  • Introduction
  • Rationale for a Second Law
    • The Direction of Natural Phenomena
    • The Feasibility of Processes
    • The Big Question: Where is the Energy Gone?

Thermodynamics: A Historical Perspective

Efficient Energy Utilization: Energy Conservation

Second Law and Entropy: A Broader View

Intermolecular Forces

Physical Properties of Pure Fluids

Thermodynamic Properties of Pure Fluids

Cubic Equations of State

Properties of Mixtures

Equilibrium and Stability

Low Pressure Vapor-Liquid Equilibrium

High Pressure Vapor-Liquid Equilibrium

Chemical Reaction Equilibrium

Elements of Statistical Mechanics

Statistical Mechanics: Application to Real Fluids